Abstract
The chemistry of the soil solution is influenced by atmospheric deposition of air pollutants, by exchange processes between the soil matrix and the soil solution and by processes between the rhizosphere and the soil. At sites of the Intercantonal Long-term Forest Observation Programme in Switzerland the soil solution has been monitored since 1998 in a number of forest plots growing from 9 to 47 sites in a wide range of soil conditions and air pollution impacts. The results show various site-specific developments of soil acidification. At sites with already advanced acidification (pH < 4.2), the acidification indicators remained rather stable at high levels, possibly due to the high buffering capacity of the aluminum buffer (pH 4.2 - 3.8). In contrast, in less acidified sites the acidification still progressed further which is reflected by e.g. the ongoing decrease of the base cation to aluminum ratio. Main driver of the acidification is the high N deposition which provokes cation loss and impedes sustainable nutrient balances for tree nutrition in the majority of plots examined. On an average for the years 2005-2017, N leaching rates were 9.4 kg N ha-1 yr-1, ranging from 0.04 to 53 kg N ha-1 yr-1. Three plots with high N input show very low N leaching, suggesting that N leaching may not always be a good eutrophication indicator. Both N deposition and N leaching have decreased since the year 2000 but the latter trend is partly also due to increased drought.
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