Arsinothricin Biosynthesis Involving a Noncanonical Radical SAM Enzyme for C-As Bond Formation
Yadi Yao, Jiale He, Fan Chen, Min Dong
This paper characterizes ArsL, a noncanonical radical SAM enzyme involved in arsinothricin biosynthesis, showing it cleaves SAM to generate an ACP radical and reconstitutes the pathway in vitro.
bioRxiv · Feb 1, 2024Biochemistry