BiochemistrybioRxivPreprint
Rate limiting release of product underlies concave Arrhenius break point of thermolysin with a Phe-Leu-Ala substrate
Jared J. Miller, Brian J. Bahnson
This paper investigates thermolysin kinetics with a tripeptide substrate and finds a concave Arrhenius break point, attributed to product release dynamics rather than catalytic steps.