BiochemistryBiochemistryPeer-reviewed
Direct Binding of Cysteine-367 Thiolate to the Active Site of the -Hydrogenase from Clostridium beijerinckii in the O2-stable State
Jifu Duan, Federica Arrigoni, Andreas Rutz…·Thomas Happe
The paper presents a high-resolution crystal structure of CbA5H in the O2-stable Hinact state, showing direct thiol binding to the active site iron, supported by DFT calculations.
DOI 10.1021/acs.biochem.6c00395